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Andalusite

Andalusite varies in colour from the pale yellowish brown to some dark bottle-green, dark brown, or typically the most popular greenish red. It's quite strong and distinctive pleochroism, to ensure that, when turned, exactly the same stone can take place yellow, green and red. Large crystals might be vertically striated prisms having a square cross-section and pyramidal ends, but they are rare. More usual are opaque, rod-like aggregates of crystals or waterworn pebbles. It's the pebbles which are usually cut as gemstones.
Andalusite is generally present in pegmatites. Pebbles occur within the gem gravels of Sri Lanka and Brazil. Other localities include Spain, Canada, Russia, Australia and the united states.
An opaque, yellowish grey variety, chiastolite, occurs so long prisms, which will make a cross when cut and polished.

Properties
Chemical Composition: Aluminium silicate with trace elements of iron or manganese. Al2SiO5
Classification / Type: Polymorphous with Kyanite and Sillimanite.
Colors / Varieties: 
  • Brown, green, yellow common. Rarely seen in pink and violet. (Green known as viridine)
  • Chiastolite is an opaque variety of andalusite which contains a black cross-like core made up of carbonaceous material in a grey - brown background.
Crystal System / Forms: Orthorhombic System / Vertically striated prisms capped with pyramids; much of the gem material as water-worn pebbles.
Hardness: 7 - 7.5
Specific Gravity: 3.18 ± 0.04
Cleavage / Fracture: Easy prismatic cleavage / Conchoidal fracture.
Optic Character: Anisotropic, D.R.; Biaxial negative.
Lustre: Vitreous.
Refractive Index / Birefringence: 1.634 - 1.643 / 0.008 - 0.013 (birefringence is highest when the indices are lowest).
Range: 1.629 - 1.664
Pleochroism: Very strong. Generally light yellow green and dark brownish red and brownish green.
Dispersion: 0.016
Magnification: Rutile needles, fingerprints, crystals. Chiastolite exhibits a dark-cross.
U.V. Fluorescence: May fluoresce dark green to yellow green under shortwave.
Spectrum: 
  • Manganese spectrum: seen at 553.5nm and fine lines at 550.5nm and 547.5nm, band at 455nm.
  • Rare earth spectrum at 580nm in some yellow, green andalusite.
Cause of Color: 
  • Green (viridine) andalusite: manganese
  • Brownish Green andalusite: charge transfer
Treatment (Enhancement): -
Specific Tests & Remarks: The strong pleochroism is often mistaken for a color change effect.
Synthesis: -
Simulants (with key separation tests): Tourmaline (optic figure, birefringence, pleochroism), Epidote (R.I., S.G.), Alexandrite (R.I., S.G., pleochroism, inclusions), Apatite (optic figure, pleochroism).
Geological Occurrence: In metamorphic rocks, within mica schist or gneiss
Sources: Sri Lanka, Spain, Brazil, Myanmar, Russia (Ural Mountains), U.S.A. (Arizona, California).
Cuts & Uses: Facetted cuts, cabochons, beads. Generally in fancy cuts to bring out its strong pleochroic property.
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